| Champ: |  Kurumi Nara |
| Runner: |  Klára Zakopalová |
| Score: | 6–1, 4–6, 6–1 |
| Before Year: | no |
See main article: 2014 Rio Open.
This was the first edition of the event. Kurumi Nara won the title, defeating Klára Zakopalová in the final, 6–1, 4–6, 6–1.
See also: 1. Klára Zakopalová (final)
See also: 2. 
Francesca Schiavone (first round)
See also: 3. 
Paula Ormaechea (quarterfinals)
See also: 4. 
Alexandra Cadanțu (first round)
See also: 5. Kurumi Nara (champion)
See also: 6. 
María Teresa Torró Flor (first round)
See also: 7. Barbora Záhlavová-Strýcová (first round)
See also: 8. 
Vania King (first round)