See main article: 2014 PTT Pattaya Open.
Maria Kirilenko was the defending champion, but decided not to participate.
Ekaterina Makarova won the title, defeating Karolína Plíšková in the final, 6–3, 7–6(9–7).
See also: 1. Sabine Lisicki (second round, withdrew because of a right shoulder injury)
See also: 2. Svetlana Kuznetsova (second round, withdrew because of a left hip injury)
See also: 3. Sorana Cîrstea (quarterfinals)
See also: 4. Ekaterina Makarova (champion)
See also: 5. Elena Vesnina (quarterfinals)
See also: 6. Garbiñe Muguruza (first round)
See also: 7. Bethanie Mattek-Sands (first round)
See also: 8. Peng Shuai (quarterfinals)