| Champ: | Ernests Gulbis |
| Runner: |  Federico Delbonis |
| Score: | 6–1, 7–6(7–5) |
| Draw: | 28 |
| Seeds: | 8 |
| Type: | singles doubles |
See main article: article and 2014 Open de Nice Côte d'Azur. Albert Montañés was the defending champion, but lost to Ernests Gulbis in the semifinals. Gulbis went on to win the title, defeating Federico Delbonis in the final, 6–1, 7–6(7–5).
The top four seeds receive a bye into the second round.
See also: 1. 
John Isner (quarterfinals)
See also: 2. Ernests Gulbis (champion)
See also: 3. 
Gaël Monfils (withdrew)
See also: 4. Gilles Simon (semifinals)
See also: 5. 
Dmitry Tursunov (quarterfinals)
See also: 6. Nicolas Mahut (second round)
See also: 7. Federico Delbonis (final)
See also: 8. Édouard Roger-Vasselin (second round)