See main article: 2014 Open GDF Suez de Limoges.
Viktorija Golubic and Magda Linette were the defending champions, having won this tournament on the ITF Women's Circuit in 2013, however, neither player chose to participate.
Kateřina Siniaková and Renata Voráčová won the title, defeating Tímea Babos and Kristina Mladenovic in the final, 2–6, 6–2, [10–5].