See main article: 2014 Open GDF Suez Nantes Atlantique.
Lucie Hradecká and Michaëlla Krajicek were the defending champions, however Krajicek chose not to participate. Hradecká partnered Andrea Hlaváčková but withdrew before their quarterfinal match.
The Ukrainian-twins Lyudmyla Kichenok and Nadiia Kichenok won the title, defeating the French-duo Stéphanie Foretz and Amandine Hesse in the final, 6–2, 6–3.