| Champ: |  Daniel Nestor Nenad Zimonjić |
| Runner: |  Bob Bryan Mike Bryan |
| Score: | 6–4, 6–2 |
See main article: 2014 Mutua Madrid Open.
Bob Bryan and Mike Bryan were the defending champions, but lost to Daniel Nestor and Nenad Zimonjić in the final, 4–6, 2–6.