See main article: 2014 Monterrey Open. Tímea Babos and Kimiko Date-Krumm were the defending champions, but chose not to participate together. Babos played alongside Olga Govortsova, while Date-Krumm teamed up with Karolína Plíšková. The two teams were scheduled to meet in the semifinals, but Date-Krumm withdrew with a right leg injury.
Darija Jurak and Megan Moulton-Levy won the title, defeating Babos and Govortsova in the final, 7–6(7–5), 3–6, [11–9].