See main article: 2014 Internazionali di Tennis Città di Vicenza. This was the first edition of the event.
Andrej Martin and Igor Zelenay won the title, defeating Błażej Koniusz and Mateusz Kowalczyk in the final, 6–1, 7–5.
Marcelo Demoliner / 
Purav Raja (first round)
Adil Shamasdin / 
Artem Sitak (first round)
James Cerretani / 
Andreas Siljeström (quarterfinals)