| Champ: |  Venus Williams |
| Runner: |  Alizé Cornet |
| Score: | 6–3, 6–0 |
| Draw: | 28 |
| Seeds: | 8 |
See main article: 2014 Dubai Tennis Championships.
Venus Williams defeated Alizé Cornet in the final, 6–3, 6–0 to win the women's singles tennis title at the 2014 Dubai Tennis Championships. It was her 45th career WTA Tour title. She also extended her winning streak at the Dubai Tennis Championships to 15 matches, having previously won when she last played in 2009 and 2010.
Petra Kvitová was the defending champion, but lost in the second round to Carla Suárez Navarro.
The top four seeds receive a bye into the second round.