See main article: 2014 Copa Colsanitas.
Jelena Janković was the defending champion, but lost to Caroline Garcia in the final, 3–6, 4–6.[1]
See also: 1. Jelena Janković (final)
See also: 2. Sloane Stephens (first round)
See also: 3. Karin Knapp (first round)
See also: 4. Anna Karolína Schmiedlová (first round)
See also: 5. Caroline Garcia (champion)
See also: 6. Vania King (semifinals)
See also: 7. Paula Ormaechea (second round)
See also: 8. Lourdes Domínguez Lino (quarterfinals)