See main article: 2014 Città di Caltanissetta.
Dominik Meffert and Philipp Oswald were the defending champions but decided not to participate.
Daniele Bracciali and Potito Starace won the title, defeating Pablo Carreño Busta and Enrique López-Pérez in the final, 6–3, 6–3.
Daniele Bracciali / Potito Starace (champions) Riccardo Ghedin / Claudio Grassi (semifinals)
Facundo Bagnis / 
Sergio Galdós (first round)