See main article: 2014 Challenger Banque Nationale de Rimouski.
Sam Groth and John-Patrick Smith were the defending champion, but they did not play together. Sam Groth played alongside Chris Guccione and lost in the quarterfinals to Ehward Corrie and Daniel Smethurst. John-Patrick Smith decided not to compete this tournament.
Edward Corrie and Daniel Smethurst won the title, defeating Germain Gigounon and Olivier Rochus in the final, 6–2, 6–1.