| Champ: |  Klára Zakopalová |
| Runner: |  Garbiñe Muguruza |
| Score: | 4–6, 7–5, 6–0 |
| Edition: | 2nd |
| Type: | singles doubles |
| Before Name: | Brasil Tennis Cup – Singles |
| After Name: | Brasil Tennis Cup – Singles |
See main article: 2014 Brasil Tennis Cup. Monica Niculescu was the defending champion, but retired in the quarterfinals against Carla Suárez Navarro.
Klára Zakopalová won the title, defeating Garbiñe Muguruza in the final, 4–6, 7–5, 6–0.
See also: 1. Carla Suárez Navarro (semifinals)
See also: 2. Garbiñe Muguruza (final)
See also: 3. Klára Zakopalová (champion)
See also: 4. 
Francesca Schiavone (first round)
See also: 5. 
Monica Niculescu (quarterfinals, retired)
See also: 6. Alexandra Cadanțu (quarterfinals)
See also: 7. María Teresa Torró Flor (first round)
See also: 8. 
Paula Ormaechea (second round)