| Champ: |  Anabel Medina Garrigues  Yaroslava Shvedova |
| Runner: |  Francesca Schiavone Sílvia Soler Espinosa |
| Score: | 7–6(7–1), 2–6, [10–3] |
| Type: | singles doubles |
See main article: 2014 Brasil Tennis Cup.
Anabel Medina Garrigues and Yaroslava Shvedova were the defending champions and successfully defended their title, defeating Francesca Schiavone and Sílvia Soler Espinosa in the final, 7–6(7–1), 2–6, [10–3].
Vania King / 
Barbora Záhlavová-Strýcová (semifinals)
Monica Niculescu / Klára Zakopalová (withdrew) Anabel Medina Garrigues / Yaroslava Shvedova (champions)