See main article: 2014 Brasil Open. Alexander Peya and Bruno Soares were the defending champions, but lost in the first round to Guillermo García-López and Philipp Oswald.
García-López and Oswald went on to win the title, defeating Juan Sebastián Cabal and Robert Farah in the final, 5–7, 6–4, [15–13].
Alexander Peya / 
Bruno Soares (first round)
Juan Sebastián Cabal / Robert Farah (final)
Horacio Zeballos (quarterfinals)