See main article: 2014 Apia International Sydney. Agnieszka Radwańska was the defending champion, but she lost in the second round to Bethanie Mattek-Sands.
Tsvetana Pironkova won her maiden WTA title, defeating Angelique Kerber in the final, 6–4, 6–4.
The top two seeds receive a bye into the second round.