| Champ: | Stanislas Wawrinka |
| Runner: |  Édouard Roger-Vasselin |
| Score: | 7–5, 6–2 |
| Type: | singles doubles |
| Draw: | 28 (4 / 3) |
| Seeds: | 8 |
| Before Name: | Aircel Chennai Open – Singles |
| After Name: | Aircel Chennai Open – Singles |
| Main Name: | Maharashtra Open |
See main article: 2014 Aircel Chennai Open. Janko Tipsarević was the defending champion, but he withdrew because of an injury.
Stanislas Wawrinka won the title, defeating Édouard Roger-Vasselin in the final, 7–5, 6–2. He did not lose a single set in the entire tournament.
The top four seeds received a bye into the second round.