See main article: 2014 Abierto Mexicano Telcel. Łukasz Kubot and David Marrero were the defending champions, but chose not to compete together. Kubot played alongside Robert Lindstedt, but lost to Feliciano López and Max Mirnyi in the quarterfinals. Marrero teamed up with Ivo Karlović, but lost to López and Mirnyi in the first round.
Kevin Anderson and Matthew Ebden won the title, defeating López and Mirnyi in the final, 6-3, 6-3.
Łukasz Kubot / 
Robert Lindstedt (quarterfinals)
Horia Tecău (first round)
Dominic Inglot (semifinals)
Eric Butorac / Raven Klaasen (quarterfinals) Daniel Kosakowski / Nicolas Meister (qualifying competition)
Adrian Mannarino / Stéphane Robert (qualified)