| Champ: |  Alexander Peya  Bruno Soares |
| Runner: |  Colin Fleming Andy Murray |
| Score: | 6–4, 7–6(7–4) |
See main article: 2013 Rogers Cup. Bob Bryan and Mike Bryan were the defending champions, but lost to Robert Lindstedt and Daniel Nestor in the quarterfinals.
All seeds receive a bye into the second round.