| Champ: |  Julien Benneteau  Nenad Zimonjić |
| Runner: |  Bob Bryan Mike Bryan |
| Score: | 4–6, 7–6(7–4), [14–12] |
| Type: | singles doubles |
See main article: 2013 Monte-Carlo Rolex Masters. Bob and Mike Bryan were the two-time defending champions but lost in the final to Julien Benneteau and Nenad Zimonjić 6–4, 6–7(4–7), [12–14].
All seeds received a bye into the second round.