The Women's 20 kilometres walk event at the 2013 European Athletics U23 Championships was held in Tampere, Finland, on 10 July.
| Gold | Lyudmyla Olyanovska | |
| Silver | Antonella Palmisano | |
| Bronze | Natalya Serezhkina |
10 July 2013
| Rank | Name | Nationality | Time | Notes | |||
|---|---|---|---|---|---|---|---|
| align=left | align=left | | |||||
| align=left | align=left | | 1:30:37 | ||||
| align=left | align=left | | 1:30:59 | PB | |||
| align=left | align=left | | 1:31:50 | ||||
| 4 | align=left | align=left | | 1:33:20 | |||
| 5 | align=left | align=left |  | 1:34:52 | |||
| 6 | align=left | align=left | | 1:37:34 | PB | ||
| 7 | align=left | align=left |  | 1:38:04 | SB | ||
| 8 | align=left | align=left | | 1:38:50 | |||
| 9 | align=left | align=left | | 1:40:10 | SB | ||
| 10 | align=left | align=left | 1:40:43 | ||||
| 11 | align=left | align=left |  | 1:41:05 | |||
| 12 | align=left | align=left | | 1:41:19 | PB | ||
| 13 | align=left | align=left |  | 1:43:51 | |||
| 14 | align=left | align=left |  | 1:45:42 | PB | ||
| 15 | align=left | align=left | 1:46:33 | ||||
| 16 | align=left | align=left | | 1:47:54 | |||
| 17 | align=left | align=left |  | 1:50:01 | |||
| 18 | align=left | align=left |  | 1:52:53 | |||
| align=left | align=left | | DQ | R 230.6a | |||
| align=left | align=left |  | DQ | R 230.6a | |||
| align=left | align=left | | DQ | R 230.6a | |||
| align=left | align=left | | DQ | R 230.6a |
Intermediate times:
2 km: 9:37 Nina Ochotnikova
4 km: 18:54 Natalya Serezhkina
6 km: 28:02 Natalya Serezhkina
8 km: 37:08 Natalya Serezhkina
10 km: 46:05 Lyudmyla Olyanovska
12 km: 55:01 Natalya Serezhkina
14 km: 1:03:36 Svetlana Vasilyeva
16 km: 1:12:21 Svetlana Vasilyeva
18 km: 1:21:09 Svetlana Vasilyeva
According to an unofficial count, 23 athletes from 12 countries participated in the event.