See main article: 2013 Brussels Open. Bethanie Mattek-Sands and Sania Mirza were the defending champions but Mattek-Sands decided not to participate.
Mirza played alongside Zheng Jie, but lost in the semifinals to Gabriela Dabrowski and Shahar Pe'er.
Anna-Lena Grönefeld and Květa Peschke won the title, defeating Dabrowski and Pe'er in the final, 6–0, 6–3.
Sania Mirza / 
Zheng Jie (semifinals)
Květa Peschke (champions)
Olga Govortsova / 
Alicja Rosolska (semifinals)