See main article: 2012 Trofeul Popeci. Diana Enache and Daniëlle Harmsen were the defending champions, but lost in the quarterfinals to Paula Kania and Irina Khromacheva, 4–6, 5–7.
Renata Voráčová and Lenka Wienerová won the title, defeating Paula Kania and Irina Khromacheva in the final, 2–6, 6–3, [10–6].