| Champ: |  Klaudia Jans-Ignacik  Kristina Mladenovic |
| Runner: |  Nadia Petrova Katarina Srebotnik |
| Score: | 7–5, 2–6, [10–7] |
See main article: 2012 Rogers Cup. Liezel Huber and Lisa Raymond were the defending champions but lost to Nadia Petrova and Katarina Srebotnik in the semifinals 6–4, 6–4.[1]
Klaudia Jans-Ignacik and Kristina Mladenovic won the title by defeating Nadia Petrova and Katarina Srebotnik 7–5, 2–6, [10–7] in the final.
The top four seeds receive a bye into the second round.