See main article: 2012 Goldwater Women's Tennis Classic.
Jamie Hampton and Ajla Tomljanović were the defending champions, but none of them took part in the 2012 tournament.
Jacqueline Cako and Natalie Pluskota won the title by defeating Eugenie Bouchard and Ulrikke Eikeri in the final, 6–3, 2–6, [10–4].