See main article: 2010 Seguros Bolívar Open Bucaramanga. Diego Álvarez and Carles Poch-Gradin were the defending champions, but they chose not to participate this year.
Pere Riba and Santiago Ventura won in the final 6 - 2, 6 - 2, against Marcelo Demoliner and Rodrigo Guidolin.
Jonathan Marray / Jamie Murray (quarterfinals)
David Marrero / Rubén Ramírez Hidalgo (first round) Pere Riba / Santiago Ventura (champions)
Marcelo Demoliner / Rodrigo Guidolin (final)