See main article: 2007 Movistar Open.
José Acasuso and Sebastián Prieto were the defending champions, but Acasuso did not participate this year. Prieto partnered Martín García, losing in the first round.
Paul Capdeville and Óscar Hernández won the title, defeating Albert Montañés and Rubén Ramírez-Hidalgo 4–6, 6–4, [10–6] in the final.
See also: 1. 
Martín García / Sebastián Prieto (first round)
See also: 2. 
Luis Horna / Sergio Roitman (first round)
See also: 3. 
Marcelo Melo / André Sá (semifinals)
See also: 4. Pablo Cuevas / Adrián García (first round, García withdrew because of a back injury)