| Champ: |  Guillermo Cañas |
| Runner: |  Juan Carlos Ferrero |
| Score: | 7–6(7–4), 6–2 |
| Type: | singles doubles |
See main article: 2007 Brasil Open.
Nicolás Massú was the defending champion, but chose not to participate that year.
Guillermo Cañas won in the final 7–6(7–4), 6–2, against Juan Carlos Ferrero.