See main article: 2006 Proximus Diamond Games.
Cara Black and Els Callens were the defending champions, but Callens did not compete this year. Black teamed up with Rennae Stubbs and lost in semifinals to Stéphanie Foretz and Michaëlla Krajicek.
Dinara Safina and Katarina Srebotnik won the title by defeating Stéphanie Foretz and Michaëlla Krajicek 6–1, 6–1 in the final.