The women's 10,000 metres walk event at the 2000 World Junior Championships in Athletics was held in Santiago, Chile, at Estadio Nacional Julio Martínez Prádanos on 20 October.
| Gold | Lyudmila Yefimkina | |
| Silver | Tatyana Kozlova | |
| Bronze | Sabine Zimmer |
20 October
| Rank | Name | Nationality | Time | Notes | |||
|---|---|---|---|---|---|---|---|
| align=left | align=left | | 44:07.74 | ||||
| align=left | align=left | | 44:24.43 | ||||
| align=left | align=left | 46:49.97 | |||||
| 4 | align=left | align=left | 47:10.96 | ||||
| 5 | align=left | align=left | 47:11.18 | ||||
| 6 | align=left | align=left |  | 47:14.79 | |||
| 7 | align=left | align=left |  | 47:57.88 | |||
| 8 | align=left | align=left |  | 48:00.84 | |||
| 9 | align=left | align=left |  | 48:48.46 | |||
| 10 | align=left | align=left |  | 49:06.47 | |||
| 11 | align=left | align=left | 49:06.91 | ||||
| 12 | align=left | align=left |  | 50:00.86 | |||
| 13 | align=left | align=left | 50:25.00 | ||||
| 14 | align=left | align=left |  | 51:30.27 | |||
| 15 | align=left | align=left |  | 52:01.94 | |||
| 16 | align=left | align=left |  | 52:03.24 | |||
| 17 | align=left | align=left |  | 52:04.46 | |||
| 18 | align=left | align=left |  | 52:09.56 | |||
| 19 | align=left | align=left |  | 52:27.20 | |||
| 20 | align=left | align=left | 53:12.90 | ||||
| 21 | align=left | align=left |  | 55:05.05 | |||
| align=left | align=left |  | DQ | ||||
| align=left | align=left |  | DQ | ||||
| align=left | align=left |  | DQ | ||||
| align=left | align=left | | DQ | ||||
| align=left | align=left | DNF | |||||
| align=left | align=left | | DNF | ||||
| align=left | align=left | DNF |
According to an unofficial count, 28 athletes from 22 countries participated in the event.