| Champ: |  Gustavo Kuerten |
| Runner: |  Marat Safin |
| Score: | 3–6, 7–6(7–2), 7–6(7–2) |
| Type: | singles doubles |
See main article: 2000 RCA Championships.
Nicolás Lapentti was the defending champion, but lost in the third round to Sébastien Grosjean.
Gustavo Kuerten won in the final 3–6, 7–6(7–2), 7–6(7–2), against Marat Safin.
The top eight seeds receive a bye into the second round.