Group 4 of the 1966 FIFA World Cup consisted of Chile, Soviet Union, Italy, and North Korea. Play began on 12 July 1966 and concluded on 20 July 1966. Soviet Union won the group and North Korea finished as runners-up on their World Cup debut, and both advanced to the quarter-finals. Italy and Chile failed to advance.[1]
| GK | 21 | Anzor Kavazashvili | |
| RB | 4 | Vladimir Ponomaryov | |
| CB | 6 | Albert Shesternyov (c) | |
| CB | 7 | Murtaz Khurtsilava | |
| LB | 3 | Leonīds Ostrovskis | |
| RH | 8 | Yozhef Sabo | |
| LH | 14 | Giorgi Sichinava | |
| OR | 11 | Igor Chislenko | |
| CF | 18 | Anatoliy Banishevskiy | |
| CF | 19 | Eduard Malofeyev | |
| OL | 15 | ||
| Manager: | |||
| Nikolai Morozov | |||
| GK | 1 | Li Chan-myung | |
| RB | 2 | Pak Li-sup | |
| CB | 3 | Shin Yung-kyoo (c) | |
| CB | 5 | Lim Zoong-sun | |
| LB | 4 | Kang Bong-chil | |
| RH | 8 | ||
| CH | 7 | Pak Doo-ik | |
| LH | 6 | Im Shung-hwi | |
| RF | 11 | Han Bong-zin | |
| CF | 10 | Kang Ryong-woon | |
| LF | 12 | Kim Seung-il | |
| Manager: | |||
| Myung Rye-hyun | |||
| GK | 1 | Enrico Albertosi | |
| SW | 22 | Sandro Salvadore (c) | |
| RB | 5 | Tarcisio Burgnich | |
| CB | 21 | Roberto Rosato | |
| LB | 6 | Giacinto Facchetti | |
| RH | 4 | Giacomo Bulgarelli | |
| LH | 13 | Giovanni Lodetti | |
| OR | 17 | Marino Perani | |
| CF | 14 | Sandro Mazzola | |
| CF | 3 | Paolo Barison | |
| OL | 19 | Gianni Rivera | |
| Manager: | |||
| Edmondo Fabbri | |||
| GK | 13 | Juan Olivares | |
| RB | 6 | Luis Eyzaguirre | |
| CB | 4 | Humberto Cruz | |
| CB | 7 | Elías Figueroa | |
| LB | 21 | Hugo Villanueva | |
| RH | 12 | Rubén Marcos | |
| LH | 14 | Ignacio Prieto | |
| OR | 1 | Pedro Araya Toro | |
| CF | 8 | Alberto Fouilloux | |
| CF | 18 | Armando Tobar | |
| OL | 17 | Leonel Sánchez (c) | |
| Manager: | |||
| Luis Álamos | |||
| GK | 13 | Juan Olivares | |
| RB | 20 | Aldo Valentini | |
| CB | 4 | Humberto Cruz | |
| CB | 7 | Elías Figueroa | |
| LB | 21 | Hugo Villanueva | |
| RH | 12 | ||
| LH | 14 | Ignacio Prieto | |
| OR | 1 | Pedro Araya Toro | |
| CF | 8 | Alberto Fouilloux | |
| CF | 11 | Honorino Landa | |
| OL | 17 | Leonel Sánchez (c) | |
| Manager: | |||
| Luis Álamos | |||
| GK | 1 | Li Chan-myung | |
| RB | 2 | Pak Li-sup | |
| CB | 3 | Shin Yung-kyoo (c) | |
| CB | 5 | Lim Zoong-sun | |
| LB | 13 | Oh Yoon-kyung | |
| RH | 8 | ||
| CH | 7 | Pak Doo-ik | |
| LH | 6 | Im Shung-hwi | |
| RF | 11 | Han Bong-zin | |
| CF | 16 | Li Dong-woon | |
| LF | 12 | Kim Seung-il | |
| Manager: | |||
| Myung Rye-hyun | |||
| GK | 1 | Lev Yashin | |
| RB | 4 | Vladimir Ponomaryov | |
| CB | 6 | Albert Shesternyov (c) | |
| CB | 7 | Murtaz Khurtsilava | |
| LB | 10 | Vasiliy Danilov | |
| RH | 8 | ||
| LH | 12 | Valery Voronin | |
| OR | 11 | Igor Chislenko | |
| CF | 19 | Eduard Malofeyev | |
| CF | 18 | Anatoliy Banishevskiy | |
| OL | 15 | Galimzyan Khusainov | |
| Manager: | |||
| Nikolai Morozov | |||
| GK | 1 | Enrico Albertosi | |
| SW | 22 | Sandro Salvadore (c) | |
| RB | 5 | Tarcisio Burgnich | |
| CB | 21 | Roberto Rosato | |
| LB | 6 | Giacinto Facchetti | |
| RH | 13 | Giovanni Lodetti | |
| CH | 4 | Giacomo Bulgarelli | |
| LH | 12 | Gianfranco Leoncini | |
| OR | 15 | Gigi Meroni | |
| CF | 14 | Sandro Mazzola | |
| OL | 16 | Ezio Pascutti | |
| Manager: | |||
| Edmondo Fabbri | |||
| GK | 1 | Li Chan-myung | |
| RB | 5 | Lim Zoong-sun | |
| CB | 3 | Shin Yung-kyoo (c) | |
| CB | 14 | Ha Jung-won | |
| LB | 13 | Oh Yoon-kyung | |
| RH | 8 | ||
| CH | 7 | Pak Doo-ik | |
| LH | 6 | Im Shung-hwi | |
| RF | 11 | Han Bong-zin | |
| CF | 17 | Kim Bong-hwan | |
| LF | 15 | Yang Song-guk | |
| Manager: | |||
| Myung Rye-hyun | |||
| GK | 1 | Enrico Albertosi | |
| SW | 9 | Francesco Janich | |
| RB | 11 | Spartaco Landini | |
| CB | 8 | Aristide Guarneri | |
| LB | 6 | Giacinto Facchetti | |
| RH | 4 | Giacomo Bulgarelli (c) | |
| LH | 7 | Romano Fogli | |
| OR | 17 | Marino Perani | |
| CF | 14 | Sandro Mazzola | |
| CF | 3 | Paolo Barison | |
| OL | 19 | Gianni Rivera | |
| Manager: | |||
| Edmondo Fabbri | |||
| GK | 21 | Anzor Kavazashvili | |
| RB | 9 | Viktor Getmanov | |
| CB | 6 | Albert Shesternyov (c) | |
| CB | 13 | Alexey Korneyev | |
| LB | 3 | Leonīds Ostrovskis | |
| RH | 12 | Valery Voronin | |
| LH | 5 | Valentin Afonin | |
| OR | 16 | Slava Metreveli | |
| CF | 2 | Viktor Serebryanikov | |
| CF | 20 | Eduard Markarov | |
| OL | 17 | Valeriy Porkujan | |
| Manager: | |||
| Nikolai Morozov | |||
| GK | 13 | Juan Olivares | |
| RB | 20 | Aldo Valentini | |
| CB | 4 | Humberto Cruz | |
| CB | 7 | Elías Figueroa | |
| LB | 21 | Hugo Villanueva | |
| RH | 12 | Rubén Marcos | |
| LH | 14 | Ignacio Prieto | |
| OR | 1 | Pedro Araya Toro | |
| CF | 11 | Honorino Landa | |
| CF | 22 | Guillermo Yávar | |
| OL | 17 | Leonel Sánchez (c) | |
| Manager: | |||
| Luis Álamos | |||