1,6-Hexanediol diacrylate explained

1,6-Hexanediol diacrylate (HDDA or HDODA) is a difunctional acrylate ester monomer used in the manufacture of polymers.[1] [2] It is particularly useful for use in ultraviolet light cure applications.[3] Furthermore, it is also used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance. Like other acrylate monomers it is usually supplied with a radical inhibitor such as hydroquinone added.[4]

Preparation

The material is prepared by acid-catalyzed esterification of 1,6-hexanediol with acrylic acid.

Other uses

As the molecule has acrylic functionality, it is capable of undergoing the Michael reaction with an amine. This allows it use in epoxy chemistry where its use speeds up the cure time considerably.[5]

See also

External links

Notes and References

  1. Web site: 1,6-Hexanediol diacrylate. PubChem. pubchem.ncbi.nlm.nih.gov. en. 2020-02-12.
  2. Web site: 1,6-Hexanediol diacrylate C12H18O4 ChemSpider. www.chemspider.com. 2020-02-12.
  3. Web site: Industrially relevant epoxy-acrylate hybrid resin photopolymerizations. Ajiboye. Gbenga. 2012. dead. https://web.archive.org/web/20131125034635/http://ir.uiowa.edu:80/cgi/viewcontent.cgi?article=3559&context=etd . 2013-11-25 .
  4. Web site: 13048-33-4 - 1,6-Hexanediol diacrylate, 99% (reactive esters), stab. with 90ppm hydroquinone - HDODA - 43203 - Alfa Aesar. www.alfa.com. 2020-02-27.
  5. Web site: Epoxy Polyacrylate Resins. www.hexion.com. 2020-02-12.