1,5-Bis(diphenylphosphino)pentane explained

1,5-Bis(diphenylphosphino)pentane is an organophosphorus compound with the formula C29H30P2. It can be prepared by reacting 1,5-dibromopentane with lithium diphenylphosphide,[1] or diphenylphosphine in presence of caesium hydroxide.[2] It reacts with copper(I) iodide to give a luminescent dinuclear complex [CuIPh<sub>2</sub>P(CH<sub>2</sub>)<sub>5</sub>PPh<sub>2</sub>]2.[3]

Notes and References

  1. Chou, Ta Shue. Yuan, Jeh Jing. Tsao, Chung Huang. Ultrasonic acceleration of the reductive cleavage of phosphorus-carbon bonds with lithium metal. A simple preparation of tertiary phosphines. Journal of Chemical Research, Synopses. 1985. 1. 18–19. 0308-2342. .
  2. Honaker . Matthew T. . Salvatore . Ralph Nicholas . A MILD AND EFFICIENT CsOH-PROMOTED SYNTHESIS OF DITERTIARY PHOSPHINES . Phosphorus, Sulfur, and Silicon and the Related Elements . Informa UK Limited . 179 . 2 . February 1, 2004 . 1042-6507 . 10.1080/10426500490262261 . 277–283. 98162486 .
  3. Zhang . Xiayi . Song . Li . Hong . Mingwei . Shi . Hongsheng . Xu . Kaijie . Lin . Qizhong . Zhao . Yi . Tian . Yuan . Sun . Jiafeng . Shu . Kangying . Chai . Wenxiang . Luminescent dinuclear copper(I) halide complexes double bridged by diphosphine ligands: Synthesis, structure characterization, properties and TD-DFT calculations . Polyhedron . Elsevier BV . 81 . 2014 . 0277-5387 . 10.1016/j.poly.2014.07.034 . 687–694.

This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "1,5-Bis(diphenylphosphino)pentane".

Except where otherwise indicated, Everything.Explained.Today is © Copyright 2009-2024, A B Cryer, All Rights Reserved. Cookie policy.